Whether a refrigerating machine is dangerous goods depends on two things: which refrigerant is charged inside it and how much is charged. Non-flammable refrigerants fall under UN 2857 (Class 2.2), flammable refrigerants under UN 3358 (Class 2.1); when the charge is less than 12 kg and the refrigeration system is sealed inside the complete unit, sea and road transport are exempt, while air transport is stricter. This guide starts from "Freon" science, breaks down refrigerant classification and equipment mapping, and explains exemption thresholds for sea/air/road transport, the Transport Dangerous Goods Appraisal Certificate required even for exempted units, and the correct SDS approach.
Refrigeration equipment (ice makers, refrigerators, air conditioners, cold-room units) is common cargo. Many companies shipping a refrigerating machine for the first time run into the same confusion: the unit carries a small amount of refrigerant inside — is it dangerous goods? Must it be declared? Can it be exempted? The answer depends on two things: ① which refrigerant is charged in the machine; ② how much is charged. This guide covers both.
1. What refrigerants exist? What exactly is "Freon"?
1.1 Freon is a family, not a single substance
"Freon" (a DuPont trademark) is the collective name for fluorine-containing halogenated hydrocarbon refrigerants, mainly composed of fluorine, chlorine and carbon (plus hydrogen). It is not a single chemical but a large family, named with R + number:
- R12 (dichlorodifluoromethane), R11 (trichlorofluoromethane) — the first generation;
- R22 (chlorodifluoromethane) — a transitional generation;
- R134a (tetrafluoroethane), R32 (difluoromethane), R410A (R32/R125 blend) — the current mainstream;
- R1234yf (tetrafluoropropene) — the next generation.
1.2 Five generations by ozone depletion / global warming potential
| Generation | Category | Representative refrigerants | Contains chlorine | ODP | GWP | Status |
|---|---|---|---|---|---|---|
| 1st | CFC (chlorofluorocarbon) | R11, R12 | Yes | High | High | Globally phased out |
| 2nd | HCFC (hydrochlorofluorocarbon) | R22 | Yes | Low | High | Transitional, being phased out |
| 3rd | HFC (hydrofluorocarbon) | R134a, R32, R410A, R404A, R407C, R125 | No | 0 | High | Current mainstream, being cut |
| 4th | HFO (hydrofluoroolefin) | R1234yf | No | 0 | Very low | Next-generation substitute |
| 5th | Natural refrigerants | R290 propane, R600a isobutane, R717 ammonia, R744 carbon dioxide | — | 0 | Very low | Back to nature, but flammable/toxic |
The evolution in one sentence: humans first used chlorine-containing CFCs (ozone-depleting) → reduced chlorine into HCFCs → removed chlorine entirely into HFCs (no ozone depletion but high GWP) → then cut GWP further toward HFOs and natural refrigerants. "Environmentally friendly" and "safety (flammability)" are in tension: the more eco-friendly a refrigerant is, the more flammable it tends to be (e.g. R290, R600a, R32) — which is exactly why transport rules pay so much attention to refrigerating machines.
1.3 China's control basis (why Freon is "sensitive")
- MEP Announcement 2005 No. 117: prohibits the import and export of industrial and commercial compressors using CFCs as refrigerant;
- Huan Han [2007] No. 200: prohibits the production, sale, import and export of household appliances using CFCs as refrigerant/foaming agent;
- The legal source of these bans is the Montreal Protocol's global phase-out mechanism for ozone-depleting substances (ODS).
2. Which refrigerants go into which equipment
The same type of equipment uses different refrigerants across eras, markets and brands. The mainstream mapping by equipment type:
| Equipment type | Mainstream refrigerants | Flammability | Corresponding class |
|---|---|---|---|
| Household refrigerator/freezer | Mainly R600a (isobutane), some R134a, R290 | R600a/R290 flammable; R134a non-flammable | R600a/R290 → 2.1; R134a → 2.2 |
| Household split air conditioner | R32 (mainstream), R410A, older R22, some R290 | R32/R290 mildly flammable; R410A/R22 non-flammable | R32/R290 → 2.1; R410A/R22 → 2.2 |
| Commercial ice maker | R404A, R134a, older R22, some R290 | R404A/R134a/R22 non-flammable; R290 flammable | R290 → 2.1; others → 2.2 |
| Central air conditioner / chiller | R410A, R134a, R407C, R22 (old) | All non-flammable | 2.2 |
| Automotive air conditioner | R134a (mainstream), R1234yf (next-gen) | R134a non-flammable; R1234yf mildly flammable | R134a → 2.2; R1234yf → 2.1 |
| Cold storage / industrial refrigeration | R717 (ammonia), R744 (CO₂), R404A | Ammonia toxic & corrosive; CO₂/R404A non-flammable | See ammonia note below |
| Reefer container / refrigerated truck | R404A, R452A, R134a | Non-flammable | 2.2 |
3. Transport exemption for equipment with different refrigerants
3.1 Classify first: is the refrigerant flammable?
There are only two dangerous goods entries for refrigerating machines, split by refrigerant flammability:
| UN number | Proper shipping name | Class | Applies to |
|---|---|---|---|
| UN 2857 | REFRIGERATING MACHINES, containing non-flammable, non-toxic gases or ammonia solutions (UN 2672) | Class 2.2 (non-flammable, non-toxic gas) | R134a, R410A, R404A, R407C, R22, R125, R227, CO₂ and other non-flammable refrigerants |
| UN 3358 | REFRIGERATING MACHINES, containing flammable, non-toxic, liquefied gas | Class 2.1 (flammable gas) | R290, R600a, R32, R1234yf and other flammable refrigerants |
3.2 Sea transport exemption (IMDG Code 42-24, Chapter 3.3)
① Non-flammable refrigerating machines (UN 2857) — exemption
Interpretation: non-flammable refrigerating machine + refrigerant charge < 12 kg (or ammonia solution < 12 L) → the whole unit is not managed as dangerous goods and can be booked as ordinary cargo.
② Flammable refrigerating machines (UN 3358) — exemption
Interpretation: flammable refrigerating machine + charge < 12 kg + pressure parts designed and tested at 3× working pressure → the whole unit is exempt, likewise not managed as dangerous goods.
3.3 Air transport exemption (IATA DGR 67)
Air rules differ from sea and are stricter. Under the IATA DGR 67 Dangerous Goods List, refrigerating machines fall into the following cases:
| Refrigerating machine case | Passenger aircraft | Cargo aircraft | Conclusion |
|---|---|---|---|
| Non-flammable machine with <12 kg non-flammable non-toxic liquefied gas, or <12 L ammonia solution ≤35% ammonia | Not Restricted | ✅ Exempt, ordinary air cargo | |
| Non-flammable machine exceeding the above exemption | Forbidden | Packing Instruction 211 | ❌ Forbidden on passenger, cargo-only under UN 2857 |
| Flammable machine (R600a/R290/R32/R1234yf, etc.) | Forbidden | Forbidden | ❌ Forbidden on both passenger and cargo aircraft |
| Machine containing ammonia >50% or toxic liquefied gas | Forbidden | ❌ Forbidden by air | |
3.4 Road transport exemption (JT/T 617-2018 / ADR / RID)
Domestic road transport follows JT/T 617 (equivalent to the UN TDG Model Regulations), and the refrigerating machine exemption is identical to sea transport (IMDG):
- Non-flammable machine: contains <12 kg of Class 2.2 gas, or <12 L ammonia solution (UN 2672) → exempt, not managed as dangerous goods;
- Flammable machine: contains <12 kg of flammable non-toxic liquefied gas, and pressure parts designed and tested at 3× working pressure → exempt.
European road (ADR) and rail (RID) share the same origin and the same 12 kg threshold.
3.5 Exemption quick reference table
| Scenario | Refrigerant flammability | Charge | Sea / Road | Air |
|---|---|---|---|---|
| Household fridge R600a, 60 g charge | Flammable | < 12 kg | ✅ Exempt | ❌ Forbidden by air |
| Household AC R32, 1.5 kg charge | Flammable | < 12 kg | ✅ Exempt | ❌ Forbidden by air |
| Commercial ice maker R404A, 8 kg charge | Non-flammable | < 12 kg | ✅ Exempt | ✅ Exempt |
| Central AC R134a, 20 kg charge | Non-flammable | ≥ 12 kg | ❌ Declare as UN 2857 | ❌ Forbidden passenger, cargo-only |
| Cold-room unit R290, 15 kg charge | Flammable | ≥ 12 kg | ❌ Declare as UN 3358 | ❌ Forbidden by air |
3.6 The appraisal certificate is still required even when exempted
Even when a refrigerating machine meets the exemption above and is not declared as dangerous goods, in practice carriers (shipping lines / airlines / fleets) and customs usually still require a《Transport Dangerous Goods Appraisal Certificate》(Cargo Transportation Condition Appraisal), issued by a qualified appraisal agency, proving the machine is "not dangerous goods" or "meets the exemption conditions".
4. How to ship equipment that cannot be exempted
When the charge is ≥ 12 kg (or the carrier requires mandatory declaration), the refrigerating machine must be shipped through the full dangerous goods process:
4.1 Determine the proper shipping name and UN number
- Non-flammable refrigerant → UN 2857, REFRIGERATING MACHINES, containing non-flammable, non-toxic gases or ammonia solutions (UN 2672), Class 2.2;
- Flammable refrigerant → UN 3358, REFRIGERATING MACHINES, containing flammable, non-toxic, liquefied gas, Class 2.1.
4.2 Documentation (three core items)
- Dangerous goods declaration / maritime declaration (submitted per the port of origin, stating UN number, class, proper shipping name and charge);
- Dangerous goods packaging certificate: the pressure container (refrigeration system) must meet packing instruction P003 + PP32, with a valid inspection certificate;
- SDS / MSDS: see the important note below.
4.3 Marking and labelling
- Dangerous goods label: the Class 2.1 (flame) or Class 2.2 (gas cylinder) label on the outer package; the UN number near the label or inside the dangerous goods mark;
- Proper shipping name marking: clearly shown on the outer package or in the shipping documents per Chapter 5.4.
4.4 Sea stowage and segregation (IMDG comparison)
| Item | UN 2857 (Class 2.2) | UN 3358 (Class 2.1) |
|---|---|---|
| EmS | F-C, S-V | F-D, S-U |
| Stowage category | Category A (deck or under deck) | Category D (deck only) |
| Segregation | General | Per Class 2.1 flammable gas segregation |
4.5 Air and road differences
- Air: IATA DGR 67 applies. When a non-flammable refrigerating machine exceeds the exemption, passenger aircraft is forbidden and cargo-only applies (Packing Instruction 211, special provision A26); flammable refrigerating machines (R290/R600a/R32/R1234yf) are forbidden on both passenger and cargo aircraft — evacuate the refrigerant first or route by sea/road.
- Domestic road: JT/T 617 series applies (equivalent to TDG), with the same classification, UN numbers and 12 kg exemption threshold.
5. Practical checklist (one page for the shipper)
- ✅ Read the nameplate: confirm refrigerant model + charge (kg);
- ✅ Judge flammability: non-flammable → Class 2.2; flammable (R290/R600a/R32, etc.) → Class 2.1;
- ✅ Check the exemption: sea/road charge < 12 kg and sealed unit → exempt; flammable refrigerating machines are forbidden by air;
- ✅ Even when exempted, obtain the Transport Dangerous Goods Appraisal Certificate (Ginga can handle it);
- ✅ Over the exemption: ≥ 12 kg → full DG declaration under UN 2857 / UN 3358, with an SDS whose subject is the refrigerating machine and Section 14 noting charge & exemption;
- ✅ Check environmental compliance: if the equipment contains CFCs such as R12/R11 → pass the ODS import/export ban first;
- ✅ Shipping refrigerant cylinders separately → declare under the corresponding refrigerant gas UN entry, no 12 kg exemption.
Appendix: regulations referenced
| Regulation / standard | Purpose |
|---|---|
| IMDG Code 42-24 (DGL Chapter 3.2, special provisions Chapter 3.3) | UN 2857 / UN 3358 entries, exemption clauses, EmS, stowage |
| IATA DGR 67 (DGL Section 4.2) | Refrigerant gas UN numbers, air exemption and forbidden rules |
| JT/T 617.3-2018 | Domestic road transport proper shipping name index |
| GB 12268-2025 List of dangerous goods | Chinese names of the UN numbers |
| Announcement 2005 No. 117 / Huan Han [2007] No. 200 | CFC refrigerant import/export ban |
| Montreal Protocol (Handbook, 14th edition) | ODS phase-out mechanism |
Need compliance advice for refrigerating machine transport?
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